Home
Class 12
CHEMISTRY
The complex [Fe(H(2)O)(5)NO]^(2+) is for...

The complex `[Fe(H_(2)O)_(5)NO]^(2+)` is formed in the 'brown ring test' for nitrates. Choose the incorrect statement for the complex.

A

Its magnetic moment is approximately 3.9 BM

B

The oxidation state of iron is `+1`

C

The hybridization of central metal ion is `sp^(3)d^(2)`

D

The brown colour of the ring is due to `d-d` transition

Text Solution

Verified by Experts

The correct Answer is:
D

`[overset(+1)(Fe) (H_(2)O)_(5) overset(+)(N)O]^(2+)`
`sp^(3) d^(2) , d^(7)` config.

3 unpaired `e^(-)`
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise E. Stability, Colour and Magnetic Properties of Complexes|60 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise F.Isomerism in Coordination Compounds|124 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise C. Werners Theory, EAN Rule|63 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Subjective Type|63 Videos
  • D-BLOCK ELEMENTS

    GRB PUBLICATION|Exercise Subjective Type|18 Videos

Similar Questions

Explore conceptually related problems

The brown ring test for nitrate employs

In the complex ion [Fe(H_(2)O)_(5)NO]^(2+)

GRB PUBLICATION-COORDINATION COMPOUNDS-D.VBT, CFT, Hybridisation
  1. Both [Ni(CO)(4)] and [Ni(CN)(4)]^(2-) are diamagnetic. The hybridisati...

    Text Solution

    |

  2. Nickel (Z=28) combines with a uninegative monodentate ligand X^(-) to ...

    Text Solution

    |

  3. The complex [Fe(H(2)O)(5)NO]^(2+) is formed in the 'brown ring test' f...

    Text Solution

    |

  4. [Fe(en)(2)(H(2)O)(2)]^(2+) +en to " complex(X)". The correct statement...

    Text Solution

    |

  5. Which of the following complexes are low spin diamagnetic ? (P) K(4)...

    Text Solution

    |

  6. Which of the following statements is incorrect ?

    Text Solution

    |

  7. For Co(II), (Choose incorrect statement):

    Text Solution

    |

  8. Which of the following are square planar complexes ? (P) [AuCl(4)]^(...

    Text Solution

    |

  9. Which of the following complexes is correctly matched with their geome...

    Text Solution

    |

  10. Which one of the following has a square planar geometry ? [At. no. Co=...

    Text Solution

    |

  11. S-1 : [Cr(NH(3))(6)]^(3+) is a inner orbital complex with S-2: The c...

    Text Solution

    |

  12. In which of the following octahedral complexes of Co (at. no. 27), wil...

    Text Solution

    |

  13. Among [Ni(CN)(4)]^(4-), [Ni(PPh(3))(3)Br] and [Ni(dmg)(2)] species, th...

    Text Solution

    |

  14. The value of 'spin only' magnetic moment for one of the following conf...

    Text Solution

    |

  15. Which of the following has dsp^(2) hybridization and is diamagnetic in...

    Text Solution

    |

  16. Which one is an outer orbital complex ?

    Text Solution

    |

  17. The geometry of [NiCl(4)]^(2-) and [Ni(PPh(3))(2)Cl(2)]are :

    Text Solution

    |

  18. The geometry ion which hs no d electrons in the central metal atom is ...

    Text Solution

    |

  19. The species having tetrahedral shape is

    Text Solution

    |

  20. Which one of the following high-spin complexes has the largest CFSE (C...

    Text Solution

    |