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The complex K(4)[Zn(CN)(4)(O(2))(2)] is ...

The complex `K_(4)[Zn(CN)_(4)(O_(2))_(2)]` is oxidised into `K_(2)[Zn(CN)_(4)(O_(2))_(2)]`, then which of the following is correct ?

A

Zn (II) is oxidised into Zn (IV)

B

Paramagnetic moment decreases

C

`O-O` bond length increases

D

Paramagnetic moment increases

Text Solution

Verified by Experts

The correct Answer is:
D

`overset(+4)K_(4)[overset(+2)Zn(overset(-4)CN)_(4)(overset(-2)O_(2))_(2)] to overset(+2)K_(2)[overset(+2)Zn(overset(-4)CN)_(4)(overset(0)O_(2))_(2)]`
`{:(" "O_(2)^(-),to," "O_(2)^(-)),("(Paramagnetic)",,"(Paramagnetic)"),(" "B.O.=1.5,," "B.O.=2.0),(" "(2u.P.e^(-)),," "(2u.P.e^(-))):}`
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