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Out of the following pairs (of complexes...

Out of the following pairs (of complexes), in which option, first complex is more stable than second complex :

A

`[Co(NO_(2))_(6)]^(4-)" and "[Co(NO_(2))_(6)]^(3-)`

B

`[Co(H_(2)O)_(6)]^(2+)" and "[Co(NH_(3))_(6)]^(2+)`

C

`[Co(trien)]^(2+)" and "[Co(en)_(2)]^(2+)`

D

`[Mn(NH_(3))_(6)]^(2+)" and "[Ni(NH_(3))_(6)]^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
C

`[Ci(trien)]^(2+)` has better chelation.
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GRB PUBLICATION-COORDINATION COMPOUNDS-E. Stability, Colour and Magnetic Properties of Complexes
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  3. Select the correct order for the wavelength of absorption for the give...

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  4. A complex K(x)[MnF(6)] has magnetic moment 4.9BM what will be the oxid...

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  5. Maximum number of atoms which are in the same plane in [Ni(CO)(4)] :

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  6. Which amongst the following has zero magnetic moment ?

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  7. Which ion has the highest magnetic moment value ?

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  8. Choose the incorrect statement :

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  9. Find pK if K is the overall complex dissociation equilibrium constant ...

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  10. Choose the correct statement for the complex [Al(H(2)O)(6)]^(3+) :

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  11. For the complex ML(2), Stepwise formation constants M+L to ML ML+L...

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  12. Which of the following complexes formed by Cu^(2+) ions is most stable...

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  13. The colour of the coordination compounds depends on the crystal field ...

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  14. The stabilization of coordination compound due to chelation is called ...

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  15. The nature of CsAuCl(3) is (this compound contains Au in two oxidation...

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  16. [Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. ...

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  17. Which of the following chemical species is tetrahedral, diamagnetic as...

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  18. The colour of Co(H(2)O)(6)^(2+) is best attributed to electronic trans...

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  19. Out of the following pairs (of complexes), in which option, first comp...

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  20. Which change in [Mn(CN)(6)]^(4-) results in symmetrical ditribution of...

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