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Consider the following statements and se...

Consider the following statements and select the correct option using the codes given.
`(i) [Cr(NH_(3))_(6)][Cr(NH)_(6)]` and `[Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)]` are coordination isomers.
`(ii)[Cr(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl` and `[Cr(py)_(2)(H_(2)O)Cl_(3)]H_(2)O` are ligand isomers.
`(iii)[Pt(NH_(3))_(4)Br_(2)]Cl_(2)` and `[Pt(NH_(3))_(4)Cl]Br_(2)` are linkage isomers.
`(iv)[NiCl_(2)(PPh_(3))_(2)(` tetrahedral`)` exhibitsgeometrical isomerism.

A

(P) only

B

(P) and (R ) only

C

(Q) and (R ) only

D

(R ) and (S) only

Text Solution

Verified by Experts

The correct Answer is:
A
(R ) `to` Ionisation isomers
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GRB PUBLICATION-COORDINATION COMPOUNDS-F.Isomerism in Coordination Compounds
  1. Which of the following complex will show optical activity ?

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  2. The complex ion . [M(en)Br(2)I(2)]^(-1), has two optical isomers. Thei...

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  3. Consider the following statements and select the correct option using ...

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  4. Which of the following has an optical isomer?

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  5. Which of the following pairs of structure shows geometrical isomerism ...

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  6. Which of the following pairs represents linkage isomers?

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  7. Select the correct statement regarding [Pt(CH(3)-CH(NH(2))COO)Cl(2)]^(...

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  8. The diamagnetic complex which has two geometrical and 4 optically acti...

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  9. The compexes [Co(NH(3))(6)][Cr(C(2)O(4))(3)] and [Cr(NH(3))(6)][Co(C(2...

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  10. Which of the following compounds show optical isomerism? I. cis -...

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  11. Which one has largest number of isomers ?

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  12. Which of the following statement is incorrect ?

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  13. Which of the following statements is not true about the complex ion [P...

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  14. Of the following complex ions, one exhibits isomerism. That is :

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  15. Which of the following will be able to show geometrical isomerism ?

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  16. The number of geometrical isomers for octahedral [Co(NH(3))(2)Cl(4)]^(...

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  17. Select the correct statement from the following :

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  18. Which of the following isomers of [M(NH(3))(2)Cl(2)] would react with ...

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  19. Which of the following is correct regarding [Pt(NH(3))(2)(CN)(2)] ?

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  20. The complex which exhibits geometrical as well as optical isomerism is...

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