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What kind of isomerism exists between [C...

What kind of isomerism exists between `[Cr(H_(2)O)_(6)]Cl_(3)` (violet) and `[Cr(H_(2)O)_(5)Cl].H_(2)O` (greyish-green)?

A

linkage isomerism

B

solvate isomerism (hydrate)

C

Polymerisation isomerism

D

co-ordination isomerism

Text Solution

Verified by Experts

The correct Answer is:
B
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Read the passage given below and answer the following questions : The existence of coordination compounds with the same formula but different arragements of the ligands was crucial in the development of coordination chemistry. Two or more compounds with the same formula but different arrangements of the atoms are called isomers. Isomers are compounds with the same molecular formula but different structural formulas and do not necessarily share similar properties. There are many different classes of isomers, like stereoisomers, enantiomers, and geometrical isomers. There are two main forms of isomerism: structural isomerism and stereoisomerism. The different chemical formulas in structural isomers are caused either by a difference in what ligands are bonded to the central atoms or how the individual ligands are bonded to the central atoms. The following questions are multiple choice questions. Choose the most appropriate answer: What kind of isomerism exists between [Cr(H_(2)O)_(6)] Cl_(3) (violet) and [Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O (greyishgreen) ?

What type of isomerism is shown by the pair [Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O ?

The compounds [Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)_(4) Cl_(2)]Cl.2H_(2)O represent

GRB PUBLICATION-COORDINATION COMPOUNDS-F.Isomerism in Coordination Compounds
  1. Which of the following complex/ion only show linkage isomerism ?

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  2. Which of the following complexes may show atleast three type of isomer...

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  3. What kind of isomerism exists between [Cr(H(2)O)(6)]Cl(3) (violet) and...

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  4. Select the complex which show both structural and stereo isomerism :

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  5. Select which is heteroleptic complex and show fac-mer isomerism :

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  6. Which of the following complex exists as dextro and laevo form ?

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  7. Which complex does not show geometrical isomerism but show optical iso...

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  8. The complex [Pt(py)(H(2)O)(NH(3))(NO(2))ClBr] has :

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  9. Which of the following statement is correct ?

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  10. Two molecules having same molecular formula are drawn for your reffere...

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  11. Indicate the complex ion which shows geometrical isomerism :

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  12. Due to the presence of ambidenate ligands coordination compounds show ...

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  13. Four statements for the following reaction given below [CoCl(2)(NH(3))...

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  14. The complex that shows optical activity is :

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  15. The correct statement on the isomerism associated with the follow...

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  16. In coordination compounds , the hydrate isomers differ in .

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  17. The phenomenon of optical activity will be shown by:

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  18. Find the pair of compounds in which both show geometrical as well as o...

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  19. Two complex compounds with same representation [CoCl(2)(NH(3))(4)]Cl h...

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  20. In which of the following pairs both the complex show optical isomeris...

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