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Which of the following metal carbonyl C-...

Which of the following metal carbonyl C-O bond length is minimum ?

A

`[V(CO)_(6)]^(-)`

B

`[Mn(CO)_(6)]^(+)`

C

`[Cr(CO)_(6)]`

D

`[Ti(CO)_(6)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
B
As charge on C.A.`darr`,C-Obond strength `uarr`, or C-O bond order `uarr`, or C-O bond length `darr`
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GRB PUBLICATION-COORDINATION COMPOUNDS-G. Organometallic Compounds, Synergic Bonding
  1. Among the following metal carbonyl carbonyl C-O bond is strongest in :

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  2. Which of the following metal carbonyl C-O bond length is minimum ?

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  3. Which of the following metal carbonyl C-O bond length is minimum ?

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  4. Which of the following is the strongest pi-acid for pi-a c c e p t o r...

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  5. The correct order of pi-acid nature is :

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  6. Consider the following complexes (P) [Cr(CO)(x)]" "(Q) [Cr(CO)(x-...

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  7. Which of the following statements is correct for Ni(CO)(4)" and "[Co(C...

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  8. Which of the following has highest C-C bond length among the following...

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  9. Wilkinson's catalyst conatains :

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  10. Which of the following has the shortest N-N bond length ?

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  11. Consider the complex given below [(NH(3))(5)overset(" II")Ru(N(2))o...

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  12. Among the following metal carbonyls the C-O bond order is lowest in .

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  13. Which of the following has maximum C-O bond length ?

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  14. If the bond length of CO bond in carbon monoxide is 1.128 Å, then what...

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  15. Among the following metal carbonyls, the C-O bond order is lowest in

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  16. Select the correct order of C-O bond length :

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  17. Which of the following has the shortest Cr-C bond length ?

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  18. Which of the following is an oxidizing agent ?

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  19. Which of the following statements is correct ?

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  20. Which options is incorrect for K(4)[Fe(CN)(6)]:

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