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Consider the following statements : St...

Consider the following statements :
Statement-1: Generally, square planar complexes show geometrical isomerism but do not exhibit optical isomerism because they do not possess plane of symmetry.
Statement-2: `Delta_(t)=(4)/(9) Delta_(0)`
Statement-3: In octahedral complexes each electron entering the `t_(2g)` orbitals stabilizes the complex ion by 0.4 `Delta_(0)` and each electron entering the `e_(g)` orbital destabilizes the complex by an amount of 0.6 `Delta_(0)`.
Select the correct statement from the codes given below.

A

Statement-1 and statement-3 are correct

B

Statement-1 and statement-3 are correct

C

Statement-1 is incorrect

D

Statement-2 and statement-3 are incorrect

Text Solution

Verified by Experts

The correct Answer is:
B, C

(a) Square planar complexes have P.O.S. which is the molecular plane itself.
(c ) `"CFSE" =-0.4 Delta_(0)xx"n"_("n"_(2g))+0.6 Delta_(0)xx"n"_("eq")+"nP"`.
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Consider the following satements : S_(1): Generally square planare complexes show geometrical isomerism but do not exhibit optical isomerism because thy do not possess plane of symmetry . S_(2): Delta_(t)=(4)/(9)Delta_(0) S_(3) : In octahedral complexes each electron entering teh t_(2g) orbitals stabilizes the complex ion by 0.4 Delta_(0) and each electron entering teh e_(g) orbital destabilizes the complex by an amount of 0.6 Delta_(0) Select the correct statement from the codes given below.

t_(2g) orbitals in octahedral complexes are

Select the complex ion which shows geometrical isomerism.

Assertion: All square planar complexes can exhibit geometrical isomerism Reason: In square planar complexes .

STATEMENT-1: Tetrahedral complexes with chiral structure exhibit optical isomerism . and STATEMENT-2: They lack plane of symmetry .

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