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Which of the following complex is hetero...

Which of the following complex is heteroleptic ?

A

`[Co(NH_(3))_(6)]Cl_(3)`

B

`PtCl_(4).4NH_(3)`

C

`PtCl_(2).4NH_(3)`

D

`PtCl_(4).3NH_(3)`

Text Solution

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The correct Answer is:
B, C, D
(b) All `Pt^(4+)` complexes have C.N.=6,`[Pt(NH_(3))_(4)Cl_(2)]Cl_(2)`
(c ) `[Pt(NH_(3))_(2)Cl_(2)].2NH_(3) " or "[Pt(NH_(3))_(4)]Cl_(2)`
(d) `[Pt(NH_(3))_(3).Cl_(3)].Cl "or " [Pt(NH_(3))_(2).Cl_(4)].NH_(3)`
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