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In which of the ion pairs, magnetic prop...

In which of the ion pairs, magnetic property depends on the strngth of ligand present in the complex ?

A

`Ti^(3+), V^(3+)`

B

`Cr^(3+), Mn^(4+)`

C

`Cr^(2+), Mn^(3+)`

D

`Mn^(2+), Fe^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
C, D

`d^(4)` to `d^(7)` configuration are affected by strength of ligand. `Cr^(2+) to d^(4),Mn^(3+) to d^(4),Mn^(2+) to d^(5),Fe^(3+) to d^(5)`
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GRB PUBLICATION-COORDINATION COMPOUNDS-MULTIPLE OBJECTIVE TYPE QUESTION
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  11. Consider following 4 complexes : (P) [Cr(CO)(5)(Pet(3))]" "(Q) [Cr...

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