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Four complexes are given : (P) [CoCl(N...

Four complexes are given :
`(P) [CoCl(NH_(3))_(5)]^(2+)" "(Q) [Co(NH_(3))_(5)(H_(2)O)]^(3+)`
`(R ) [Co(NH_(3))_(6)]^(3+)" "(S) [Co(CN)_(6)]^(3-)`
All of them exhibit at least one of the following 4 colours viz, violet, red, yellow orange, pale yellow. One of them absorbs light in the U.V. region.
Choose the correct statement(s).

A

Order of wavelength of light absorbed : `PgtQgtRgtS`

B

S must be violet in colour

C

R must have absorbed wavelength of blue colour light

D

Q must be pale yellow in colour

Text Solution

Verified by Experts

The correct Answer is:
A, C

Order of `Delta_(0) : (S) gt (R ) gt (Q) gt (P), Delta_(0) prop(1)/(lambda_(abs))`
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