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Choose the correct statement(s) :

A

`[Co(NH_(3))_(6)]^(2+)` is an inner orbital complex whereas `[Ni(NH_(3))_(6)]^(2+)` is an outer orbital complex

B

`[Fe(H_(2)O)_(6)]^(3+)` is strongly paramagnetic whereas `[Fe(CN)_(6)]^(3-)` is weakly paramagnetic.

C

`[Ni(CO)_(4)]` is tetrahedral and paramagnetic

D

`[NiCl_(4)]^(2-)` is tetrahedral and diamagnetic

Text Solution

Verified by Experts

The correct Answer is:
A, B

`[Ni(CO)_(4)]` is diamagnetic.
`[NiCl_(4)]^(2-)` is paramagnetic.
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GRB PUBLICATION-COORDINATION COMPOUNDS-MULTIPLE OBJECTIVE TYPE QUESTION
  1. Four complexes are given : (P) [CoCl(NH(3))(5)]^(2+)" "(Q) [Co(NH(...

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  2. In which of the following, the central metal atom is behaving as a lew...

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  3. Choose the correct statement(s) :

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  4. In Pt(C(2)H(4))(2)(C(2)F(4))(2) molecule, in which the platinum and al...

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  5. Which of the chelating ligands maintain hapticity equal to denticity ?

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  6. Consider following 4 complexes : (P) [Cr(CO)(5)(Pet(3))]" "(Q) [Cr...

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  7. VBT model for [MnCo(CO)(9)] suggests :

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  8. Which of the following are paramagnetic ?

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  9. Which of the following can show coordination isomerism ?

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  10. Which is/are correct statement(s)?

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  11. Atomic number of Mn. Fe and Co are 25, 26 and 27 respectively. Which o...

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  12. Atomic number of Mn, Fe, Co and Ni are 25, 26, 27 and 28 respectively....

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  13. Which of the following options are correct for [Fe(CN)(6)]^(3-) comple...

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  14. An aqueous pink solution of cobalt (II) chloride changes to deep blue ...

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  15. Which of the following complexes are homoleptic ?

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  16. Which of the following complexes are heteroleptic ?

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  17. Identify the optically active compounds from the following :

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  18. Identify the correct statements for the behaviour of ethane-1, 2-diami...

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  19. Which of the following complexes show linkage isomerism ?

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  20. Which of the following complex(es) is paramagnetic as well as low spin...

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