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Molecule AB has a bond length of 1.617Å ...

Molecule AB has a bond length of `1.617Å` and a dipole moment of 0.38 D. The fractional charge on each atom (absolute magnitude) is :
`(e_(0)=4.802xx10^(-10)"esu")`

A

0

B

`1.0`

C

`0.5`

D

`0.05`

Text Solution

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The correct Answer is:
To find the fractional charge on each atom in molecule AB, we can follow these steps: ### Step 1: Convert Bond Length to Centimeters The bond length is given as \(1.617 \, \text{Å}\). We need to convert this to centimeters. \[ 1 \, \text{Å} = 10^{-8} \, \text{cm} \] \[ \text{Bond Length (L)} = 1.617 \, \text{Å} = 1.617 \times 10^{-8} \, \text{cm} \] ### Step 2: Convert Dipole Moment to Centimeters The dipole moment is given as \(0.38 \, \text{D}\). We convert this to the appropriate units. \[ 1 \, \text{D} = 3.335 \times 10^{-30} \, \text{C m} = 1 \times 10^{-18} \, \text{esu cm} \] \[ \text{Dipole Moment} (\mu) = 0.38 \, \text{D} = 0.38 \times 10^{-18} \, \text{esu cm} \] ### Step 3: Use the Dipole Moment Formula The dipole moment (\(\mu\)) is related to the charge (\(Q\)) and the bond length (\(L\)) by the formula: \[ \mu = Q \times L \] Rearranging this gives us: \[ Q = \frac{\mu}{L} \] ### Step 4: Substitute Values to Find Q Substituting the values we have: \[ Q = \frac{0.38 \times 10^{-18} \, \text{esu cm}}{1.617 \times 10^{-8} \, \text{cm}} \] ### Step 5: Calculate Q Calculating the above expression: \[ Q = \frac{0.38 \times 10^{-18}}{1.617 \times 10^{-8}} = 0.2347 \times 10^{-10} \, \text{esu} \] ### Step 6: Calculate the Fractional Charge The fractional charge on each atom can be found by dividing the charge \(Q\) by the elementary charge \(e_0\): \[ e_0 = 4.802 \times 10^{-10} \, \text{esu} \] Thus, the fractional charge \(q\) is: \[ q = \frac{Q}{e_0} = \frac{0.2347 \times 10^{-10} \, \text{esu}}{4.802 \times 10^{-10} \, \text{esu}} \] ### Step 7: Calculate the Fractional Charge Calculating the above expression gives: \[ q \approx 0.0488 \] ### Conclusion The absolute magnitude of the fractional charge on each atom is approximately \(0.05\).

To find the fractional charge on each atom in molecule AB, we can follow these steps: ### Step 1: Convert Bond Length to Centimeters The bond length is given as \(1.617 \, \text{Å}\). We need to convert this to centimeters. \[ 1 \, \text{Å} = 10^{-8} \, \text{cm} \] ...
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