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When the carbon-oxygen bonds in H(3)COH,...

When the carbon-oxygen bonds in `H_(3)COH,H_(2)CO, and HCO_(2)^(-)` are arranged in order of increasing length, what is the correct order?

A

`H_(3)COH,H_(2)CO,HCO_(2)^(-)`

B

`HCO_(2)^(-),H_(3)COH,H_(2)CO`

C

`H_(2)CO,HCO_(2)^(-),H_(3)COH`

D

`H_(3)COH,HCO_(2)^(-),H_(2)CO`

Text Solution

Verified by Experts

The correct Answer is:
C

`{:(CH_(3)-O-H,,H-overset(O)overset(||)C-H,,H-overset(O)overset(||)C-H,H-overset(O)overset(||)C-O^(Theta)harrH-overset(" "O^(Theta))overset(|)C=O),(" I"," II"," III"):}`
I has single bond character while II has double bond character and III has partial double bond character, Hence B.L. order : II lt III lt I.
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GRB PUBLICATION-CHEMICAL BONDING-I-F.Resoncance
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  13. For which species are both bonds of equal length? (P) ClO(2)^(-) (...

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  14. The nitrite ion can be represented, {:(,"I."[:overset(..)underset(.....

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  15. In which species is resonance most useful in explaining the observed b...

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