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Which of the following compounds may hav...

Which of the following compounds may have a `P-P` bond :

A

`H_(4)P_(2)O_(5)`

B

`(HPO_(3))_(3)`

C

`H_(4)P_(2)O_(7)`

D

`H_(4)P_(2)O_(6)`

Text Solution

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The correct Answer is:
To determine which of the given compounds may have a P-P bond, we will analyze each compound's structure step by step. ### Step 1: Analyze Compound A - H4P2O5 1. **Count the Atoms**: The formula indicates there are 2 phosphorus (P) atoms, 4 hydrogen (H) atoms, and 5 oxygen (O) atoms. 2. **Draw the Structure**: The structure can be drawn with two phosphorus atoms connected by oxygen atoms and hydrogen atoms attached to phosphorus. 3. **Check for P-P Bond**: In this structure, we find that there is no direct P-P bond; instead, there is a P-O-P linkage. **Hint for Step 1**: Look for direct connections between phosphorus atoms in the structure. ### Step 2: Analyze Compound B - HPO3 (thrice) 1. **Count the Atoms**: The formula indicates there is 1 phosphorus atom and 3 oxygen atoms in a cyclic arrangement. 2. **Draw the Structure**: The cyclic structure shows phosphorus bonded to three oxygen atoms. 3. **Check for P-P Bond**: There are no P-P bonds present; only P-O bonds are observed. **Hint for Step 2**: Identify if the phosphorus is part of a cyclic structure and how it connects to oxygen. ### Step 3: Analyze Compound C - H4P2O7 1. **Count the Atoms**: The formula indicates there are 2 phosphorus atoms, 4 hydrogen atoms, and 7 oxygen atoms. 2. **Draw the Structure**: The structure can be drawn with two phosphorus atoms, connected through oxygen atoms and surrounded by hydrogen. 3. **Check for P-P Bond**: In this structure, there is no direct P-P bond; only P-O bonds are present. **Hint for Step 3**: Ensure to visualize the connectivity between phosphorus and oxygen atoms clearly. ### Step 4: Analyze Compound D - H4P2O6 1. **Count the Atoms**: The formula indicates there are 2 phosphorus atoms, 4 hydrogen atoms, and 6 oxygen atoms. 2. **Draw the Structure**: The structure can be drawn with two phosphorus atoms directly connected to each other, along with oxygen and hydrogen atoms. 3. **Check for P-P Bond**: In this structure, there is a direct P-P bond present, along with P-O bonds. **Hint for Step 4**: Look for direct connections between phosphorus atoms without intermediaries like oxygen. ### Conclusion After analyzing all four compounds, we find that only **H4P2O6** contains a P-P bond. Therefore, the correct answer is **D - H4P2O6**.

To determine which of the given compounds may have a P-P bond, we will analyze each compound's structure step by step. ### Step 1: Analyze Compound A - H4P2O5 1. **Count the Atoms**: The formula indicates there are 2 phosphorus (P) atoms, 4 hydrogen (H) atoms, and 5 oxygen (O) atoms. 2. **Draw the Structure**: The structure can be drawn with two phosphorus atoms connected by oxygen atoms and hydrogen atoms attached to phosphorus. 3. **Check for P-P Bond**: In this structure, we find that there is no direct P-P bond; instead, there is a P-O-P linkage. **Hint for Step 1**: Look for direct connections between phosphorus atoms in the structure. ...
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  4. Which of the following oxy-acid consists of S-S linkage and both sulph...

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  5. Which of the following compounds may have a P-P bond :

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  6. Which of the following oxide/oxy-anions does not contain P-O-P linkage...

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  7. Which of the following oxyacid/oxysalt/compound does not contain perox...

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  8. (P) on removal of one mole water produces (Q) underset("An oxyacid")...

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  9. Oxyacid which have same number of X-H and X-OH bonds is (where X is ce...

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  10. How many valence electrons are in the pyrophosphate ion, P(2)O(7)^(4-)...

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  11. What is the oxidation of state of S in H(2)SO(5) and H(2)S(2)O(8) ?

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  12. The peroxymonosulphate anion, HSO(5)^(-), has :

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  15. Which of the following species has ring structure but not six membered...

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  17. The correct statement is :

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  18. The total number of sigma- bonds in P(6)O(18)^(6-) ion is :

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  19. Compound which is not an oxyacid is :

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  20. P(4)O(10) has short and long P-O bonds. The number of short P-O bonds ...

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