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Hybridisation of PCl(5) solid is :...

Hybridisation of `PCl_(5)` solid is :

A

`sp_(3)`

B

`sp^(3)d^(2)`

C

`sp^(2)`

D

`dsp^(2)`

Text Solution

Verified by Experts

The correct Answer is:
A, B
`underset(sp^(3))(PCl_(4)^(+))" "underset(sp^(3)d^(2))(PCl_(6)^(-))`
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Describe hybridisation in the case of PCl_(5) and SF_(6) The axial bonds are longer as compared to equatorial bonds in PCl_(5) whereas in SF_(6) both axial bonds and equatorial bonds and have the same bond length. Explain.

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GRB PUBLICATION-CHEMICAL BONDING-I-Multiple Objective Type
  1. Which of the following has more than four 90^(@) bond angle among foll...

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  2. Which of the following species are pyramidal in shape?

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  3. Hybridisation of PCl(5) solid is :

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  4. From octahedral geometry of central atom which of the following shape ...

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  5. Which of the following species has X-O-X linkage? (X = central atom)

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  6. Na(2)S(4)O(6) and Na(2)S(3)O(6) compounds are different in :

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  7. In which of the following X-O-X bonds are present? [X = P, S, Cr]

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  8. d-orbital used by 'S' in SF(6) molecule are :

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  9. Which of the following d-orbital participates in the hybridization of ...

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  10. Which have linear structure?

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  11. Correct order regarding bond angle in the following species?

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  12. Which of the following has cyclic structure?

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  13. In which of the following cases the number of lone pairs on central at...

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  14. The compounds having 8 or more bond angles equal to 90^(@), are :

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  15. Consider the structure of (CH(3)COOH)(2) given below : Select the...

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  16. Which of the following have non-zero dipole moment?

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  17. Select the compounds which have polyatomic anion in their solid state?

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  18. In which of the following all the hybrid orbitals lie at same angle to...

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  19. Which of the following statement is/are correct about P(4)O(10) molecu...

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  20. Select the correct statement.

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