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A system performs work DeltaW when an am...

A system performs work `DeltaW` when an amount of heat is `DeltaQ` added to the system, the corresponding change in the internal energy is `DeltaU` . A unique function of the initial and final states (irrespective of the mode of change) is

A

`DeltaQ`

B

`DeltaW`

C

`DeltaU`and `DeltaU`

D

`DeltaU`

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The correct Answer is:
To solve the problem, we need to identify a unique function of the initial and final states of a thermodynamic system, which is independent of the path taken to change from the initial state to the final state. ### Step-by-Step Solution: 1. **Understanding the Problem**: - We are given that a system performs work \( \Delta W \) when an amount of heat \( \Delta Q \) is added to it, resulting in a change in internal energy \( \Delta U \). - We need to find a unique function that depends only on the initial and final states of the system, not on how the system transitions from one state to another. 2. **Applying the First Law of Thermodynamics**: - The First Law of Thermodynamics states: \[ \Delta U = \Delta Q - \Delta W \] - Here, \( \Delta U \) is the change in internal energy, \( \Delta Q \) is the heat added to the system, and \( \Delta W \) is the work done by the system. 3. **Identifying the Unique Function**: - The change in internal energy \( \Delta U \) is a state function. This means it depends only on the initial and final states of the system, regardless of the path taken to get from one state to the other. - In contrast, \( \Delta Q \) and \( \Delta W \) are not state functions; they depend on the specific process or path taken. 4. **Conclusion**: - Therefore, the unique function of the initial and final states, irrespective of the mode of change, is: \[ \Delta U \] - This indicates that the change in internal energy is the only quantity that is a function of the state of the system, independent of how the transition occurs. ### Final Answer: The unique function of the initial and final states is \( \Delta U \) (the change in internal energy). ---
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