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One mole of an ideal monoatomic gas is h...

One mole of an ideal monoatomic gas is heated at a constant pressure of one atmosphere from`0^(@)` to `100^(@)C.` Then the change in the internal energy is

A

`6.56`joules

B

`8.32xx10^(2)`joules

C

`12.48xx10^(2)`joules

D

`20.80joules`

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The correct Answer is:
To solve the problem of finding the change in internal energy of one mole of an ideal monoatomic gas heated at constant pressure from \(0^\circ C\) to \(100^\circ C\), we can follow these steps: ### Step 1: Understand the relationship between heat, work, and internal energy According to the first law of thermodynamics, we have: \[ \Delta Q = \Delta U + \Delta W \] where: - \(\Delta Q\) is the heat added to the system, - \(\Delta U\) is the change in internal energy, - \(\Delta W\) is the work done by the system. ### Step 2: Identify the process In this case, the gas is heated at constant pressure. For a constant pressure process, the work done by the gas can be expressed as: \[ \Delta W = P \Delta V \] where \(P\) is the pressure and \(\Delta V\) is the change in volume. ### Step 3: Use the specific heat at constant pressure For an ideal gas, the heat added at constant pressure can be expressed as: \[ \Delta Q = n C_p \Delta T \] where: - \(n\) is the number of moles, - \(C_p\) is the specific heat at constant pressure, - \(\Delta T\) is the change in temperature. ### Step 4: Calculate \(\Delta T\) The change in temperature from \(0^\circ C\) to \(100^\circ C\) is: \[ \Delta T = 100 - 0 = 100 \, \text{°C} = 100 \, \text{K} \] ### Step 5: Determine \(C_p\) for a monoatomic gas For a monoatomic ideal gas, the specific heat at constant pressure is given by: \[ C_p = \frac{5}{2} R \] where \(R\) is the universal gas constant (\(R \approx 8.31 \, \text{J/(mol·K)}\)). ### Step 6: Calculate \(\Delta Q\) Substituting the values into the heat equation: \[ \Delta Q = n C_p \Delta T = 1 \cdot \frac{5}{2} R \cdot 100 \] \[ \Delta Q = 1 \cdot \frac{5}{2} \cdot 8.31 \cdot 100 \] \[ \Delta Q = 5 \cdot 8.31 \cdot 50 \] \[ \Delta Q = 2077.5 \, \text{J} \] ### Step 7: Calculate the change in internal energy For an ideal gas, the change in internal energy is related to the change in temperature: \[ \Delta U = n C_v \Delta T \] where \(C_v\) for a monoatomic gas is: \[ C_v = \frac{3}{2} R \] Thus, \[ \Delta U = 1 \cdot \frac{3}{2} R \cdot 100 \] \[ \Delta U = 1 \cdot \frac{3}{2} \cdot 8.31 \cdot 100 \] \[ \Delta U = 3 \cdot 8.31 \cdot 50 \] \[ \Delta U = 1246.5 \, \text{J} \] ### Final Answer The change in internal energy is: \[ \Delta U = 1246.5 \, \text{J} \approx 1.25 \times 10^3 \, \text{J} \]
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