Home
Class 12
CHEMISTRY
Be shows diagonal relationship with Al. ...

Be shows diagonal relationship with Al. Disicuss.

Text Solution

Verified by Experts

The ionic radius of `Be^(2+)` is nearly the same as the of `Al^(3+)` ion. Hence beryllium resembles aluminium in some properties.
(1) Both beryllium and aluminium are not readily attacked by acids, beacause of the presence of an oxide film on the surface of the metal.
(2) Hydroxides of both beryllium and aluminium are amphoteric and dissolve in both acids and bases. with bases `Be(OH)_(2)` forms beryllate ion `[Be(OH)_(4)]^(2-)` while `Al(OH)_(3)` forms aluminate ion `[Al(OH)_(4)]^(-)`.
(3) The chlorides of both beryllium and aluminium have chloride bridge bonds in vapour phase. Both the chlorides are soluble in organic solvents and are strong Lewis acids. These are used as Friedel Craft catalysis.
(4) Beryllium and aluminium ions have strong tendency to form complexes `BeF^(-2)_(4), AlF_(6)^(3-)`.
Promotional Banner

Topper's Solved these Questions

  • THE s-BLOCK ELEMENTS

    VGS PUBLICATION-BRILLIANT|Exercise Long Answer Question (8 Marks)|25 Videos
  • THE s-BLOCK ELEMENTS

    VGS PUBLICATION-BRILLIANT|Exercise Long Answer Question (8 Marks)|25 Videos
  • THE p-BLOCK ELEMENTS-GROUP 14

    VGS PUBLICATION-BRILLIANT|Exercise LONG ANSWER QUESTIONS|7 Videos
  • THERMODYNAMICS

    VGS PUBLICATION-BRILLIANT|Exercise ADDITIONAL QUESTIONS & ANSWERS|6 Videos

Similar Questions

Explore conceptually related problems

Beryllium shows diagonal relationship with aluminium. Which one of the following similarity is not correct?

Silicon has diagonal relationship with

Boron exhibits diagonal relationship with

Boron exhibits diagonal relationship with

In what respects does Li show diagonal relationship with Mg?

Diagonal relationship is shown by

Aluminium exhibits diagonal relationship with

Aluminium exhibits diagonal relationship with

VGS PUBLICATION-BRILLIANT-THE s-BLOCK ELEMENTS -Short Answer Questions (4 Marks)
  1. Give an account of the properties of washing soda.

    Text Solution

    |

  2. Mention some uses of sodium carbonate.

    Text Solution

    |

  3. How do you obtain pure sodium chloride from a crude sample?

    Text Solution

    |

  4. What do you know about Castner-Kellner process? Write the principle in...

    Text Solution

    |

  5. Write a few applications of caustic soda.

    Text Solution

    |

  6. Give an account of the biological importance of Na^(+) and K^(+) ions.

    Text Solution

    |

  7. Mention the important uses of Mg metals.

    Text Solution

    |

  8. Show that Be(OH)(2) is amphoteric in nature.

    Text Solution

    |

  9. Write a note on the anomalous behaviour of beryllium.

    Text Solution

    |

  10. Be shows diagonal relationship with Al. Disicuss.

    Text Solution

    |

  11. What is Plaster of Paris? Write a short note on it.

    Text Solution

    |

  12. In what ways lithium shows similarities to magnesium in its chemical b...

    Text Solution

    |

  13. When an alkali metal dissolves in liquid ammonia the solution can acqu...

    Text Solution

    |

  14. What happens when (i) Sodium metal is dropped in water?

    Text Solution

    |

  15. What happens when (ii) Sodium metal is heated in a free supply of ai...

    Text Solution

    |

  16. What happens when (iii) Sodium peroxide dissolves in water ?

    Text Solution

    |

  17. State as to why (i) An aqueous solution of Na(2)CO(3) is alkaline.

    Text Solution

    |

  18. State as to why (ii) Alkali metals are prepared by the electrolysis ...

    Text Solution

    |

  19. How would you expalain the following observation? (i)BeO is almost i...

    Text Solution

    |

  20. How would you expalain the following observation? (ii)BaO is soluble...

    Text Solution

    |