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With the help of fthermondynamic equatio...

With the help of fthermondynamic equation of state
`((delU)/(delV))_(T)=T((delP)/(delT))_(V)-P`
Answer the following questions for a van der Waals' gas
`P=(nRT)/(V-nb)-(an^(2))/V^(2)`
` DeltaH` for the insothermal process from `(P_(1)V_(1)T)`to `(P_(2)V_(2)T)` to is :

A

`DeltaH=(P_(2)V_(2)-P_(1)V_(1))`

B

`DeltaH=-an^(2)((1)/V_(2)-(1)/V_(1))+(P_(2)V_(2)-P_(1)V_(1)`

C

`DeltaH =-an^(2)(1/V_(2)-(1)/V_(1))+nRT[(V_(2))/(V_(2)-nb)-(V_(1))/(V_(1)-nb)]`

D

`DeltaH=nRT[(V_(2))/(V_(2)-nb)-(V_(1))/(V_(1)-nb)]`

Text Solution

Verified by Experts

The correct Answer is:
b,c
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