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The cell reaction 2Ag^+(aq)+H2(g)to2H^+(...

The cell reaction `2Ag^+(aq)+H_2(g)to2H^+(aq)+2Ag(s)`,best represented by :

A

`Ag(s)|Ag^+"(aq)"||"H^+(aq)|H_2(g)|Pt(s)`

B

`Pt(s)|H_2(g)|H^+(aq)"||"Ag^+(aq)|Ag(s)`

C

`Ag(s)|Ag^+"(aq)"||"H_2(g)|H^+(aq)|Pt(s)`

D

`Ag^+"(aq)"|"Ag(s)||H_2(g)|H^+(aq)`

Text Solution

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The correct Answer is:
To represent the cell reaction \(2Ag^+(aq) + H_2(g) \rightarrow 2H^+(aq) + 2Ag(s)\), we can follow these steps: ### Step 1: Identify the Anode and Cathode In a galvanic cell, oxidation occurs at the anode and reduction occurs at the cathode. - **Oxidation**: In the given reaction, \(H_2(g)\) is oxidized to \(2H^+(aq)\). - **Reduction**: \(Ag^+(aq)\) is reduced to \(Ag(s)\). ### Step 2: Assign the Half-Reactions From the overall cell reaction, we can write the half-reactions: - **Oxidation half-reaction**: \[ H_2(g) \rightarrow 2H^+(aq) + 2e^- \] - **Reduction half-reaction**: \[ 2Ag^+(aq) + 2e^- \rightarrow 2Ag(s) \] ### Step 3: Determine the Electrode Materials - For the oxidation half-reaction involving \(H_2\), we will use a **platinum electrode** as it is inert and can facilitate the reaction. - For the reduction half-reaction involving \(Ag^+\), we will use a **silver electrode**. ### Step 4: Write the Cell Representation The cell representation follows the format: \[ \text{Anode} | \text{Anode Solution} || \text{Cathode Solution} | \text{Cathode} \] 1. **Anode**: \(Pt(s) | H_2(g) | H^+(aq)\) 2. **Cathode**: \(Ag^+(aq) | Ag(s)\) Combining these, we get: \[ Pt(s) | H_2(g) | H^+(aq) || Ag^+(aq) | Ag(s) \] ### Step 5: Finalize the Cell Representation The complete cell representation is: \[ Pt(s) | H_2(g) | H^+(aq) || Ag^+(aq) | Ag(s) \] ### Conclusion The best representation of the cell reaction \(2Ag^+(aq) + H_2(g) \rightarrow 2H^+(aq) + 2Ag(s)\) is: \[ Pt(s) | H_2(g) | H^+(aq) || Ag^+(aq) | Ag(s) \]
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