The `E^(@)` at `25^(@)`C for the following reaction is 0.55 V. Calculate the `DeltaG^(@)` in kJ`//`mol : `4BiO^(+)(aq)+3N_(2)H_(5)^(+)to4Bi(s)+3N_(2)(g)+4H_(2)O(l)+7H^(+)`
A
`-637`
B
`-424`
C
`-106`
D
`-318.5`
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The correct Answer is:
A
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Diborane is a potential rocket fuel which undergoes combustion according to the reaction, B_(2)H_(6) (g) + 3O_(2) (g) rarr B_(2) O_(3) (s) + 3H_(2) O (g) From the following data, calculate the enthalpy change for the combustion of diborane: (i) 2 B (s) + ((3)/(2)) O_(2) (g) rarr B_(2) O_(3) (s) , Delta H = 0 1273 k J//mol (ii) H_(2) (g) + ((1)/(2)) O_(2) (g) rarr H_(2) O (l), Delta H = -286 kJ//mol (iii) H_(2) O (l) rarr H_(2)O (g) Delta H = 44 kJ//mol (iv) 2B (s) + 3H_(2) (G) rarr B_(2) H_(6) (g), Delta H = 36 kJ//mol