If the equilibrium constant for the reaction `Cd^(2+)(aq)+4NH_3(aq)iffCd(NH_3)_4^(2+)(aq)` is `10^x` then find the value of x. (Given: `E_(Cd^(2+)"|"Cd)^(@)=-0.4V,E_(Cd(NH_3)_4^(2+)"|"Cd)^(@)=-0.61V`)
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The equilibrium constant for the reaction : Co^(3+)(aq) + 6NH_3(aq) hArr [Co(NH_3)_6]^(3+) (aq) is 2.0xx10^(-7) . Calculate the value of DeltaG^@ at 25^@C
Corrosion is essentially an electrochemical phenomenon. Explain the reactions occurring during corrosion of iron kept in an open atmosphere. (b) Calculate the equilibrium constant for the equilibrium reaction Fe_((s)) + Cd_((aq))^(2+) hArr Fe_((aq))^(2+) + Cd_((s)) (Given : E_(Cd^(2+)|Cd)^(@) = -0.40 V , E_(Fe^(2+)|Fe)^(@) = -0.44V ).
(a) Express the relationship amongst cell constant , resistance of the solution in the cell and conductivity of the solution . How is molar conductivity of a solute related to conductivity of its solution ? (b) Calculate the equilibrium constant for the reaction Fe_((s)) + Cd_((aq))^(2+) hArr Fe_((aq))^(2+) + Cd (s) (Given : E_(Cd^(2+)|Cd)^(@) = 0.40 V , E_(Fe^(2+) |Fe)^(@) = -0.44 V ).
Write the Nernst equation for the reaction : 2Cr(s)+3Cd^(2+)(aq) to 2Cr^(3+)(aq)+3Cd(s)
Find the equilibrium constant at 298K for the reaction, Cu^(2+)(aq) +In^(2+)(aq)hArr Cu^(+)(aq) +In^(3+)(aq) Given that E_(Cu^(2+)//Cu^(+))^(@) =0.15V, E_(In^(3+)//In^(-))^(@) =- 0.42V, E_(In^(2+)//In^(+))^(@) =- 0.40V
Calculate the equilibrium constant for the reaction : Fe(s)Cd^(2+)(aq)harrFe^(2+)(aq)+Cd(s) ("Given" E_(cd^(2+)//Cd)^(@)=-0.40 V, E_(Fe^(2+)//Fe)^(@)=-0.44 V)
Calculate equilibrium constant for the reaction : Zn+Cd^(2+) hArr Zn^(2+)+Cd , (Given E_(cell)^(@)=0.36 "V " )
calculate the value of equilibrium constant (K_f) for the reaction: Zn^(2+)(aq)+4OH^(-)(aq)iffZn(OH)_4^(2-)(aq) Given: Zn^(2+)(aq)+2e^(-)toZn(s0,E^(@)=-0.76 V Zn(OH)_4^(2-)(aq)+2e^(-)toZn(s)+4OH^(-)(aq),E^(@)=-1.36 V 2.303(RT)/F=0.06