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For a reaction A rarr B, E(a) = 10 kJ mo...

For a reaction `A rarr B, E_(a) = 10 kJ mol^(-1), DeltaH = 5 kJ mol^(-1)`. Thus, potential energy profile for this reaction is:

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To solve the problem regarding the potential energy profile for the reaction \( A \rightarrow B \) with given values of activation energy (\( E_a = 10 \, \text{kJ mol}^{-1} \)) and enthalpy change (\( \Delta H = 5 \, \text{kJ mol}^{-1} \)), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Definitions**: - **Activation Energy (\( E_a \))**: This is the minimum energy required for a reaction to occur. The given \( E_a = 10 \, \text{kJ mol}^{-1} \) is for the forward reaction. - **Enthalpy Change (\( \Delta H \))**: This indicates whether a reaction is exothermic or endothermic. A positive \( \Delta H = 5 \, \text{kJ mol}^{-1} \) means the reaction is endothermic. 2. **Determine the Activation Energy for the Backward Reaction**: - We can use the relationship: \[ \Delta H = E_a^{\text{forward}} - E_a^{\text{backward}} \] - Plugging in the values: \[ 5 = 10 - E_a^{\text{backward}} \] - Rearranging gives: \[ E_a^{\text{backward}} = 10 - 5 = 5 \, \text{kJ mol}^{-1} \] 3. **Sketch the Potential Energy Profile**: - On the y-axis, represent potential energy. - Start with the potential energy of reactant \( A \) at a certain level. - Draw a peak at the activation energy for the forward reaction, which is \( 10 \, \text{kJ mol}^{-1} \) above the energy level of \( A \). - From the peak, drop down to the energy level of product \( B \). Since \( \Delta H = 5 \, \text{kJ mol}^{-1} \), the energy level of \( B \) will be \( 5 \, \text{kJ mol}^{-1} \) higher than that of \( A \). 4. **Label the Diagram**: - Label the starting point as \( A \), the peak as the transition state, and the endpoint as \( B \). - Indicate the activation energy for the forward reaction (\( E_a^{\text{forward}} = 10 \, \text{kJ mol}^{-1} \)) and the activation energy for the backward reaction (\( E_a^{\text{backward}} = 5 \, \text{kJ mol}^{-1} \)). 5. **Conclusion**: - The potential energy profile illustrates that the reaction is endothermic, as the products are at a higher energy level compared to the reactants.
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