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Hydrogenation of alkyne is...

Hydrogenation of alkyne is

A

Addition reaction

B

Elimination reaction

C

Rearrangement reaction

D

Substitution reaction

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The correct Answer is:
A

Alkynes have triple bond.
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Hydrogenation of alkenes and alkynes takes place in presence of certain catalysts. In Sabatier Senderen's reaction, the addition of hydrogen takes place I presence of Raney nickel catalyst. Platininm and palladium can also be used as catalyst and used in finley divided state. Experimentally, it is observed that less crowded alkenes adsorb H_(2) with faster rate. Controlled hydrogenation of alkyne H_(2) with faster rate. Controlled hydrogenation of alkyne in presence of Lindlar's catalyst yields cis product i.e., 'cis' alkene. Thus, in presence of Lindlar's catalyst 'syn' addition takes place. The relative rate of hydrogenation follows the order: Non-terminal alkynes are reduced in presence of Na or Li metal dissolved in liquid ammonia. In this reaction, anti-addition of hydrogen results into the trans-product. Answer the following questions: The relative rate of catalytic hydrogenation of following alkenes is:

Hydrogenation of alkenes and alkynes takes place in presence of certain catalysts. In Sabatier Senderen's reaction, the addition of hydrogen takes place I presence of Raney nickel catalyst. Platininm and palladium can also be used as catalyst and used in finley divided state. Experimentally, it is observed that less crowded alkenes adsorb H_(2) with faster rate. Controlled hydrogenation of alkyne H_(2) with faster rate. Controlled hydrogenation of alkyne in presence of Lindlar's catalyst yields cis product i.e., 'cis' alkene. Thus, in presence of Lindlar's catalyst 'syn' addition takes place. The relative rate of hydrogenation follows the order: Non-terminal alkynes are reduced in presence of Na or Li metal dissolved in liquid ammonia. In this reaction, anti-addition of hydrogen results into the trans-product. H_(3)C-C-=C-CH_(3)+H_(2) overset(Pd//CaCO_(3))underset("Boiling Quinoline")to (A) The product (A) will be:

MARVEL PUBLICATION-BASIC PRINCIPLES AND TECHNIQUES IN ORGANIC CHEMISTRY-Test your grasp
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  9. The enolic form of butanone contains

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  11. Which of the following is observed in ethylene nw lecule?

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  12. Orbital interaction ( partial overlapping ) between the sigma bonds of...

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  13. Carbocation which is most stable is

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  14. No bond resonance explains the stability of the following :

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  15. Which of the following pairs is an example of position isomerism?

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  16. Diethyl ether and methyl n propyl ether are

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  17. 2-Pentanone and 3-methyl-2-butanone are a pair of isomers.

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  19. two substances when separated out on the basis of their extent of adso...

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  20. Isomers have essentially identical :

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  21. IUPAC name of CH(2)=CH-CH(CH(3)CH(2))underset(Br)underset(|)C=CH(2) is

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