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Methanoic acid, the first member of carb...

Methanoic acid, the first member of carboxylic acid series, when warmed with concentrated sulphuric acid decompose in the following way and evolve carbon monoxide.

The driving force for this reaction lies in the fact that the `HC-=O^(+)` ion is very unstable acid and thus easily loses `H^(+)`.
If formic acid is replaced by benzoylformic acid, `C_6 H_5 COCOOH` the product formed will be

A

`C_(6)H_(5)CO OH+CO+CO_(2)`

B

`C_(6)H_(5)CO OH+CO_(2)`

C

`C_(6)H_(5)CO OH+CO`

D

`C_(6)H_(5)CHO+CO_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

`C_(6)H_(5)COCO OH overset(H_(2)SO_(4))underset(Delta)toC_(6)H_(5)CO OH+CO`
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NARAYNA-CARBOXYLIC ACID-All Questions
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  2. Methanoic acid, the first member of carboxylic acid series, when warme...

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  3. Methanoic acid, the first member of carboxylic acid series, when warme...

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  4. Consider the pathway of a well known organic reaction For the con...

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  5. Consider the pathway of a well known organic reaction Which step ...

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  6. Match the column {:("Column I (Acid)","Column II " (pK(a) "Value"))...

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  7. Match the column {:("Column I","Column II"),"(A) Acetic acid","(p) d...

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  9. Statement 1: Carboxylic acids do not give characterstic reactions of c...

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  10. Statement 1 : Carboxylic acids have higher boiling points than alkanes...

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  11. Statement 1 : Pure acetic acid can be converted into ice like solid ca...

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  12. Statement 1 : Lower acids on reacting with strong electropositive meta...

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  13. consider the reaction CH(3)OH+CO overset("Cobalt carbonyl")underset...

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  14. Consider What is the value of n?

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  15. A dicarboxylic acid of the form does not undergo decarboxylation...

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  16. Find the total number of products obtained when Undergoes decarbo...

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  17. Find the total number of different products obtained when is heat...

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  18. Citric acid contains X carboxylic groups and Y hydroxy groups. Value o...

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  19. Where X is

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