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Nitrogen gas is kept in an open beaker a...

Nitrogen gas is kept in an open beaker at 273 K and 1 atm pressure. If the pressure of the surrounding suddenly falls to 0.5 atm and the temperature increases to 546 K, then the percentage of nitrogen remaining in the beaker is `mn%` of the initial amount. Then the value of m+n is:

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To solve the problem, we will use the ideal gas law and the concept of moles of gas under different conditions. ### Step-by-Step Solution: 1. **Identify Initial Conditions**: - Initial Temperature (T1) = 273 K - Initial Pressure (P1) = 1 atm - Initial number of moles of nitrogen (N1) = N (assume N moles) 2. **Identify Final Conditions**: - Final Temperature (T2) = 546 K - Final Pressure (P2) = 0.5 atm - Final number of moles of nitrogen (N2) = ? 3. **Use the Ideal Gas Law**: The ideal gas law states that \( PV = nRT \). Since the volume (V) is constant (the beaker is open), we can set up the equation as follows: \[ \frac{P_1 V}{N_1 T_1} = \frac{P_2 V}{N_2 T_2} \] Since V is constant, we can cancel it out: \[ \frac{P_1}{N_1 T_1} = \frac{P_2}{N_2 T_2} \] 4. **Rearranging the Equation**: Rearranging gives us: \[ N_2 = N_1 \cdot \frac{P_2 T_1}{P_1 T_2} \] 5. **Substituting Values**: Substitute the known values into the equation: \[ N_2 = N \cdot \frac{0.5 \cdot 273}{1 \cdot 546} \] Simplifying this: \[ N_2 = N \cdot \frac{0.5 \cdot 273}{546} \] \[ N_2 = N \cdot \frac{136.5}{546} \] \[ N_2 = N \cdot \frac{1}{4} = 0.25N \] 6. **Calculating the Percentage of Nitrogen Remaining**: The percentage of nitrogen remaining in the beaker is given by: \[ \text{Percentage} = \left(\frac{N_2}{N_1}\right) \times 100 = \left(\frac{0.25N}{N}\right) \times 100 = 25\% \] 7. **Identifying m and n**: From the percentage of nitrogen remaining, we have: - \( mn\% = 25\% \) - Here, \( m = 2 \) and \( n = 5 \). 8. **Calculating m + n**: \[ m + n = 2 + 5 = 7 \] ### Final Answer: The value of \( m + n \) is **7**.
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