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The root mean spuare (rms) speed of hydr...

The root mean spuare (rms) speed of hydrogen molecules at a certain temperature is 300m/s. If the temperature is doubled and hydrogen gas dissociates into atomic hydrogen the rms speed will become

A

`424.26m//s`

B

`300m//s`

C

`600m//s`

D

`150m//s`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the new root mean square (rms) speed of hydrogen atoms after the temperature is doubled and the hydrogen gas dissociates into atomic hydrogen. ### Step-by-step Solution: 1. **Understand the rms speed formula**: The rms speed \( V_{rms} \) is given by the formula: \[ V_{rms} = \sqrt{\frac{3RT}{M}} \] where \( R \) is the universal gas constant, \( T \) is the temperature in Kelvin, and \( M \) is the molar mass of the gas. 2. **Initial conditions**: We know that the initial rms speed of hydrogen molecules (H₂) at a certain temperature is \( 300 \, \text{m/s} \). The molar mass of hydrogen molecule (H₂) is \( 2 \, \text{g/mol} \) or \( 0.002 \, \text{kg/mol} \). 3. **Doubling the temperature**: If the temperature is doubled, we denote the initial temperature as \( T \) and the final temperature as \( 2T \). 4. **Dissociation of hydrogen**: When hydrogen gas (H₂) dissociates into atomic hydrogen (H), the molar mass changes. The molar mass of atomic hydrogen (H) is \( 1 \, \text{g/mol} \) or \( 0.001 \, \text{kg/mol} \). 5. **New rms speed calculation**: We need to find the new rms speed \( V'_{rms} \) for atomic hydrogen at the new temperature: \[ V'_{rms} = \sqrt{\frac{3R(2T)}{M'}} \] where \( M' \) is the molar mass of atomic hydrogen. 6. **Relating initial and final speeds**: We can relate the initial and final rms speeds using the formula: \[ \frac{V_{initial}}{V_{final}} = \frac{T_{initial}}{T_{final}} \cdot \frac{M_{final}}{M_{initial}} \] Plugging in the values: \[ \frac{300}{V'_{rms}} = \frac{T}{2T} \cdot \frac{1}{2} \] Simplifying gives: \[ \frac{300}{V'_{rms}} = \frac{1}{2} \cdot \frac{1}{2} = \frac{1}{4} \] 7. **Solving for \( V'_{rms} \)**: \[ 300 = \frac{1}{4} V'_{rms} \] Therefore: \[ V'_{rms} = 300 \times 4 = 1200 \, \text{m/s} \] 8. **Final answer**: The new rms speed of atomic hydrogen after doubling the temperature is \( 1200 \, \text{m/s} \).
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