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Two moles of helium are mixed with n mol...

Two moles of helium are mixed with n moles of hydrogen. The root mean spure (rms) speed of the gas molecules in the mexture is `sqrt2` times the speed of sound in the mixture. Then value of n is

A

1

B

3

C

2

D

`3//2`

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To solve the problem, we need to find the value of \( n \) when two moles of helium are mixed with \( n \) moles of hydrogen, and the root mean square (rms) speed of the gas molecules in the mixture is \( \sqrt{2} \) times the speed of sound in the mixture. ### Step-by-Step Solution: 1. **Understanding the Given Information**: - We have 2 moles of helium (He) and \( n \) moles of hydrogen (H₂). - The rms speed of the gas mixture is \( \sqrt{2} \) times the speed of sound in the mixture. 2. **Formulas**: - The rms speed \( v_{rms} \) of a gas is given by: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \] where \( R \) is the universal gas constant, \( T \) is the temperature, and \( M \) is the molar mass of the gas mixture. - The speed of sound \( v_s \) in a gas is given by: \[ v_s = \sqrt{\frac{\gamma RT}{M}} \] where \( \gamma \) is the adiabatic index (ratio of specific heats). 3. **Setting Up the Relationship**: - According to the problem, we have: \[ v_{rms} = \sqrt{2} v_s \] - Substituting the formulas for \( v_{rms} \) and \( v_s \): \[ \sqrt{\frac{3RT}{M}} = \sqrt{2} \sqrt{\frac{\gamma RT}{M}} \] 4. **Simplifying the Equation**: - Squaring both sides gives: \[ \frac{3RT}{M} = 2 \cdot \frac{\gamma RT}{M} \] - Canceling \( RT/M \) (assuming \( RT/M \neq 0 \)): \[ 3 = 2\gamma \] - Therefore, we find: \[ \gamma = \frac{3}{2} \] 5. **Finding the Molar Mass of the Mixture**: - The molar mass \( M \) of the mixture can be calculated using the formula: \[ M = \frac{n_1M_1 + n_2M_2}{n_1 + n_2} \] - Here, \( n_1 = 2 \) (moles of He), \( M_1 = 4 \, \text{g/mol} \) (molar mass of He), \( n_2 = n \) (moles of H₂), \( M_2 = 2 \, \text{g/mol} \) (molar mass of H₂): \[ M = \frac{2 \cdot 4 + n \cdot 2}{2 + n} = \frac{8 + 2n}{2 + n} \] 6. **Calculating \( \gamma \) for the Mixture**: - The expression for \( \gamma \) is given by: \[ \gamma = \frac{C_p}{C_v} = 1 + \frac{R}{C_v} \] - We can express \( C_v \) for the mixture: \[ C_v = \frac{C_{v1}n_1 + C_{v2}n_2}{n_1 + n_2} \] - Where \( C_{v1} = \frac{3}{2}R \) for He and \( C_{v2} = \frac{5}{2}R \) for H₂: \[ C_v = \frac{\frac{3}{2}R \cdot 2 + \frac{5}{2}R \cdot n}{2 + n} = \frac{3R + \frac{5}{2}Rn}{2 + n} \] 7. **Substituting \( C_v \) into \( \gamma \)**: - Now substituting \( C_v \) into the equation for \( \gamma \): \[ \frac{3}{2} = 1 + \frac{R}{\frac{3R + \frac{5}{2}Rn}{2 + n}} \] - Rearranging gives: \[ \frac{1}{2} = \frac{R(2 + n)}{3R + \frac{5}{2}Rn} \] 8. **Cross Multiplying and Simplifying**: - Cross-multiplying gives: \[ (3R + \frac{5}{2}Rn) = 2R(2 + n) \] - Expanding and simplifying: \[ 3R + \frac{5}{2}Rn = 4R + 2Rn \] - Rearranging terms: \[ \frac{5}{2}Rn - 2Rn = 4R - 3R \] - This simplifies to: \[ \frac{1}{2}Rn = R \] - Therefore: \[ n = 2 \] ### Final Answer: The value of \( n \) is \( 2 \).
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