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Assertion: BF(3) is weaker lewisi acid t...

Assertion: `BF_(3)` is weaker lewisi acid than `BC l_(3)`.
Reason: `BF_(3)` is less electron deficient thann `BCl_(3)`.

A

If both (A) and (R) are true and (R) is the correct explanation of (A)

B

if both (A) and (R) are true but (R) is not correct explanation of (A)

C

If (A) is true but (R) is false

D

If (A) is false but (R) is false

Text Solution

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The correct Answer is:
A
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Explain why BF_(3) is a weaker Lewis acid than BCl_(3) .

BCl_(3) is an electron-deficient compound.

Statement-1 BF_(3) is a weaker Lewis acid than BCl_(3) Statement -2: BF_(3) molecule is stabilized to a greater extent than BCl_(3) by p pi -p pi back bonding.

Assertion BF_(3) is a weaker Lewis acid than BCI_(3) Reasoning In BF_(3) molecule, back bonding (ppi-ppi) is stronger than in BCI_(3) .

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