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Assertion: There is a very little differ...

Assertion: There is a very little difference in acidic strengths of `H_(3)PO_(4),H_(3)PO_(3)` and `H_(3)PO_(2)`.
reason: Number of unprotonated oxygen (=O) responsible for increase of acidic strength due to inductive effective remains the same.

A

If both (A) and (R) are true and (R) is the correct explanation of (A)

B

if both (A) and (R) are true but (R) is not correct explanation of (A)

C

If (A) is true but (R) is false

D

If (A) is false but (R) is false

Text Solution

Verified by Experts

The correct Answer is:
A

Reason is the correct explanation of the assertion.
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The sum of bascities of H_(3)PO_(4), H_(3)PO_(3) and H_(3)PO_(2) is

There is very little difference in acid strength in the series H_3 PO_4, H_3 PO_3 and H_2 PO_2 because

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What should be the order of acidic strength in the series H_(3)PO_(4) , H_(3)PO_(3) , and H_(3)PO_(2) ?

Assertion (A): There is very little difference in acid strength of H_(3)PO_(4), H_(3)PO_(3) ,and H_(3)PO_(2) . Reason (R) : The hydrogens in these acids are not all bonded to oxygens. The electrone-grativities of P and H are almost the same.

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