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Statement-I : PCl(5) "and" PbCl(4) are t...

Statement-I : `PCl_(5) "and" PbCl_(4)` are thermally unstable.
Statement-II : They produce same gas on thermal decomposition

A

If both (A) and (R) are true and (R) is the correct explanation of (A)

B

if both (A) and (R) are true but (R) is not correct explanation of (A)

C

If (A) is true but (R) is false

D

If (A) is false but (R) is false

Text Solution

Verified by Experts

The correct Answer is:
B, C

`PCl_(5)overset(Delta)toPCl_(3)+Cl_(2)`
`PCl_(5)` decomposes into `PCl_(3)` and `Cl_(2)` as in its structure two P-Cl axial bonds are longer than other three P-Cl equatorial bonds.
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