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A very dilute acidic solution of Cd^(2+)...

A very dilute acidic solution of `Cd^(2+) and Ni^(2+)` gives only yellow ppt. of CdS on passing `H_(2)S`, this is due to

A

Solubility product `(K_(sp))` of CdS is more than that of NiS

B

Solubility product `(K_(sp))` of CdS is less than that of NiS

C

`Cd^(2+)` belong to IIB group while `Ni^(2+)` belongs to `IV^(th)` group

D

CdS is insoluble in yellow ammonium sulphide (YAS)

Text Solution

Verified by Experts

The correct Answer is:
B

Basic radicals are classified on the basis of increasing order of `K_(sp)Cd^(2+)` in II group while `Ni^(2+)` in IV group.
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A very dilute acidic solution of Cd^(2+)&Ni^(2+) gives only yelllwo ppt. of CdS on passing H_(2)S , this is due to:

Statement I A very dilute acidic solution of Cd^(2+) and Ni^(2+) gives yellow precipitate of CdS on passing H_(2)S . Statement II Solubility product of CdS is more than that of NiS .

Assertion (A): A is very dilute acidic solution of Cd^(2+) and Ni^(2+) gives yellow precipitate of CdS on passing hydrogen sulphide. Reason (R) : Solubility product of CdS is more than that of NiS .

Identify(A) based on followihng facts : a. A reduces HgCl_(2) solution to white ppt. charging to grey . b. (A) turns FeCl_3 yellow colured solution to green . c. (A) givewhite pot, with NaOH soluble ine xcess fo NaOH . ltrgt d. (A) gives yellow dirty ppt. on passing H_2S gs , soluble in yellow ammium sulpjde (YAS). e. (A) gives chromyl chloride test .

VK JAISWAL-QUALITATIVE INORGANIC ANALYSIS-LEVEL 2
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