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Select correct statement(s): (I) When ...

Select correct statement(s):
(I) When excess `FeCl_(3)` solution is added to `K_(4)[Fe(CN)_(6)]` solution, in addition to `Fe^(III)[Fe^(II)(CN)_(6)]^(-),Fe^(II)[Fe^(III)(CN)_(6)]^(-)` is also formed due to side redox reaction
(II) When `FeCl_(2)` is added to `K_(3)[Fe(CN)_(6)]` solution, in addition to `Fe^(II)[Fe^(III)(CN)_(6)]^(-),Fe^(III)[Fe^(II)(CN)_(6)]^(-)` is also formed due to side redox reaction.
(III) `Fe^(III)[Fe^(II)(CN)_(6)]^(-)` is paramagnetic while `Fe^(II)[Fe^(III)(CN)_(6)]^(-)` is diamagnetic.
(IV) `Fe^(III)[Fe^(II)(CN)_(6)]^(-)` is diamagnetic while `Fe^(II)[Fe^(III)(CN)_(6)]^(-)` is paramagnetic

A

I,II

B

III,IV

C

both (a) and (b)

D

none of these

Text Solution

Verified by Experts

The correct Answer is:
A
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