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(i) An aqueous solution of a compound (A...

(i) An aqueous solution of a compound (A) is acidic towards litmus and (A) sublimes at about `300^(@)C`.
(ii) (A) on treatment with an excess of `NH_(4)SCN` gives a red coloured compound (B) and on treatment with a solution of `K_(4)[Fe(CN)_(6)]` gives a blue coloured compound (C).
(iii) (A) on heating with excess of `K_(2)Cr_(2)O_(7)` in the presence of concentrated `H_(2)SO_(4)` evolves deep red vapours of (D).
(iv) On passing the vapour of (D) into a solution of NaOH and then adding the solution of acetic acid and lead acetate, a yellow precipitate of compound (E) is obtained.
Identify (A) to (E) and give chemical equations for the reactions.

A

`+VI`

B

`+V`

C

`+III`

D

`-II`

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Identify A to C. (a). An aqueous solution of a compoud (A) is acidic towards litmus and (A) is sublimed at about 300^@C . (b). (A) on treatment with an excess of NH_4CNC gives a red coloured compound (B) and on treatment with a solution of K_4Fe(CN)_6 gives a blue coloured compound (C).

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VK JAISWAL-QUALITATIVE INORGANIC ANALYSIS-LEVEL 3
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