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In a closed system : A(s)hArr 2B(g)+3C, ...

In a closed system : `A(s)hArr 2B(g)+3C`, if the partial pressure of C is doubled, then partial pressure of B will be

A

two times the original pressure

B

one half of its original value

C

`(1)/(2sqrt2)` times to the original value

D

`2sqrt2` times to the original value

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AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given reaction and how the change in the partial pressure of one of the products affects the other product. The reaction is: \[ A(s) \rightleftharpoons 2B(g) + 3C(g) \] ### Step-by-Step Solution: 1. **Identify the Reaction and Kp Expression**: The equilibrium constant \( K_p \) for the reaction can be expressed as: \[ K_p = \frac{(P_B)^2 (P_C)^3}{1} \] where \( P_B \) is the partial pressure of gas B and \( P_C \) is the partial pressure of gas C. The solid A does not appear in the expression since its activity is considered to be 1. 2. **Initial Conditions**: Let the initial partial pressures of B and C be \( P_B \) and \( P_C \) respectively. 3. **Change in Partial Pressure of C**: According to the problem, the partial pressure of C is doubled: \[ P_C' = 2P_C \] 4. **Set Up the New Kp Expression**: With the new partial pressure of C, the equilibrium constant expression becomes: \[ K_p = (P_B')^2 (P_C')^3 = (P_B')^2 (2P_C)^3 \] Simplifying this gives: \[ K_p = (P_B')^2 \cdot 8P_C^3 \] 5. **Equate the Two Kp Expressions**: Since \( K_p \) remains constant, we can set the two expressions for \( K_p \) equal to each other: \[ (P_B)^2 (P_C)^3 = (P_B')^2 \cdot 8P_C^3 \] 6. **Cancel Out Common Terms**: Since \( P_C^3 \) is common in both sides, we can cancel it out (assuming \( P_C \neq 0 \)): \[ (P_B)^2 = (P_B')^2 \cdot 8 \] 7. **Solve for \( P_B' \)**: Taking the square root of both sides gives: \[ P_B = P_B' \cdot \sqrt{8} \] Rearranging this, we find: \[ P_B' = \frac{P_B}{\sqrt{8}} = \frac{P_B}{2\sqrt{2}} \] ### Conclusion: The new partial pressure of B, \( P_B' \), when the partial pressure of C is doubled, is: \[ P_B' = \frac{P_B}{2\sqrt{2}} \] ### Final Answer: The partial pressure of B will be \( \frac{1}{2\sqrt{2}} \) times its original pressure. ---
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