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The electronic configurationo of Cu(II) ...

The electronic configurationo of Cu(II) is `3d^(9)` whereas that of Cu(I) is `3d^(10)`. Which of the following is correct ?

A

Cu(I) is more stable

B

Cu(II) is less stable

C

Cu(I) and Cu(II) are equally stable

D

Stability of Cu(I) and Cu(II) depends on nature of copper salts

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The correct Answer is:
To determine the stability of Cu(I) and Cu(II) based on their electronic configurations, we can follow these steps: ### Step 1: Understand the Electronic Configurations - The electronic configuration of Copper (Cu) in its neutral state is: - \( [Ar] 3d^{10} 4s^1 \) - When Copper loses one electron to form Cu(I), the configuration becomes: - \( [Ar] 3d^{10} \) - When Copper loses two electrons to form Cu(II), the configuration becomes: - \( [Ar] 3d^{9} \) ### Step 2: Analyze Stability Based on Electronic Configuration - A fully filled \( d \) subshell (like \( 3d^{10} \)) is more stable than a partially filled \( d \) subshell (like \( 3d^{9} \)). - Therefore, Cu(I) with the configuration \( 3d^{10} \) is more stable than Cu(II) with the configuration \( 3d^{9} \). ### Step 3: Evaluate the Given Statements 1. **Copper(I) is more stable, Copper(II) is less stable**: This statement is correct based on the analysis above. 2. **Copper(I) and Copper(II) are equally stable**: This statement is incorrect as we established that Cu(I) is more stable. 3. **Stability of Copper(I) and Copper(II) depends on the nature of copper salts**: This statement is also incorrect since the stability is primarily determined by the electronic configuration, not the nature of the salts. ### Conclusion Based on the analysis: - The correct statements are: - Copper(I) is more stable than Copper(II). - Copper(II) is less stable than Copper(I). ### Final Answer The correct option is: - **Copper(I) is more stable, Copper(II) is less stable.** ---

To determine the stability of Cu(I) and Cu(II) based on their electronic configurations, we can follow these steps: ### Step 1: Understand the Electronic Configurations - The electronic configuration of Copper (Cu) in its neutral state is: - \( [Ar] 3d^{10} 4s^1 \) - When Copper loses one electron to form Cu(I), the configuration becomes: - \( [Ar] 3d^{10} \) - When Copper loses two electrons to form Cu(II), the configuration becomes: ...
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