(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute `H_(2)SO_(4)` gives a pink coloured compound `(C )`. `(iii)` The aqueous solution of (A) on treatment with NaOH and `Br_(2)-` water gives a compound (D). (iv) A solution of (D) in conc. `HNO_(3)` on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same coloure at that of (C). (v) A solution of (A) on treatment with a solution of barium chloride gave a white precipitate of compound (F) Which was insoluble in conc. `HNO_(3)` and conc. HCl. Which of the following is true for compound (C ).
A
It oxidises ammonia to nitrogen dioxide in neutral medium.
B
It's pink colour is due to d-d transition
C
It can be oxidised by ozone.
D
It is obtained by alkaline fusion of pyrolusite in presence of air followed by electrolytic oxidation
Text Solution
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The correct Answer is:
D
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