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(i) A powdered substance (A) on treatmen...

(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute `H_(2)SO_(4)` gives a pink coloured compound `(C )`.
`(iii)` The aqueous solution of (A) on treatment with NaOH and `Br_(2)-` water gives a compound (D).
(iv) A solution of (D) in conc. `HNO_(3)` on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same coloure at that of (C).
(v) A solution of (A) on treatment with a solution of barium chloride gave a white precipitate of compound (F) Which was insoluble in conc. `HNO_(3)` and conc. HCl.
Which of the following is true for compound (C ).

A

It oxidises ammonia to nitrogen dioxide in neutral medium.

B

It's pink colour is due to d-d transition

C

It can be oxidised by ozone.

D

It is obtained by alkaline fusion of pyrolusite in presence of air followed by electrolytic oxidation

Text Solution

Verified by Experts

The correct Answer is:
D

Conceptual
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