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N(0)//2 atoms of X(g) are converted into...

`N_(0)//2` atoms of X(g) are converted into `X^(+)` (g) by energy `E_(1) . N_(0)//2` atoms of X(g) are converted into `X^(-)` (g) by the energy `E_(2)` . Hence ionisation potential and electron affinity of X(g) are :

A

`(2E_(1))/(N_(0)) , (2(E_(1) - E_(2)))/(N_(0))`

B

`(2E_(1))/(N_(0)) , (2E_(2))/(N_(0))`

C

`((E_(1) - E_(2)))/(N_(0)) , (2E_(2))/(N_(0))`

D

`(E_(1))/(N_(0)) , (2E_(2))/(N_(0))`

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To solve the problem, we need to determine the ionization potential and electron affinity of the element X based on the given information about the conversion of its atoms into ions. ### Step-by-Step Solution: 1. **Understanding the Problem**: We have `N_0/2` atoms of X(g) being converted into `X^(+)` (g) using energy `E_1`. We also have `N_0/2` atoms of X(g) being converted into `X^(-)` (g) using energy `E_2`. We need to find the ionization potential and electron affinity of X(g). 2. **Ionization Energy Calculation**: - The ionization energy (IE) is the energy required to remove an electron from a neutral atom to form a cation. - Given that `N_0/2` atoms of X are converted into `X^(+)` using energy `E_1`, the energy required to ionize one atom of X can be calculated as: \[ \text{Ionization Energy (IE)} = \frac{2E_1}{N_0} \] - This is because the total energy `E_1` is used for `N_0/2` atoms, and we need to find the energy per atom. 3. **Electron Affinity Calculation**: - The electron affinity (EA) is the energy released when an electron is added to a neutral atom to form an anion. - Similarly, for the conversion of `N_0/2` atoms of X into `X^(-)` using energy `E_2`, the energy per atom can be calculated as: \[ \text{Electron Affinity (EA)} = \frac{2E_2}{N_0} \] - Again, this is derived from the total energy `E_2` used for `N_0/2` atoms. 4. **Final Expressions**: - Therefore, the final expressions for the ionization potential and electron affinity of X(g) are: \[ \text{Ionization Potential} = \frac{2E_1}{N_0} \] \[ \text{Electron Affinity} = \frac{2E_2}{N_0} \] ### Summary of Results: - Ionization Potential of X(g): \(\frac{2E_1}{N_0}\) - Electron Affinity of X(g): \(\frac{2E_2}{N_0}\)
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The amount of energy required to remove the most loosely bound electron from an isolated gaseous atom is called as first ionization energy (IE_(1)) . Similarly the amount of energies required to knock out second, third etc. electrons from the isolated and IE_(3)gt IE_(2)gt IE_(1) . (i) Nuclear charge (ii) Atomic size (iii) penetration effect of the electrons (iv) shielding effect of the inner electrons and (b) electronic configurations (exactly half filled and completely filled configurations are extra stable) are the important factors which affect the ionisation energies. Similarly, the amount of energy released when a neutral isolated gaseous atom accepts an extra electron to from gaseous anion is called electron affinity. (X(g)+e^(-)(g)rarr X^(-)(g)+ energy A positive elecrton affinity idicates that the ion X^(-) has a lower more negative energy than the neutral atom X. The second electron affinity for the addition of a second electron to an initially neutral atom is negative because the electron replusion outweights the nuclear attraction, e.g., O(g)+e^(-)overset("Exothermic")rarr O^(-)(g),E_(a)=+141 kJ mol^(-) ....(i) O^(-)(g)+e^(-)overset("Excothermic")rarr, E_(a)=-780 kJ mol^(-) ...(ii) The electron affinity of an element depends upon (i) atomic size (ii) nuclear charge and (iii) electronic configuration. In general, in a group, ionisation energy and electron affinity decrease as the atomic size increases. The members of third period have some higher (e.g., S and Cl) electron affinity values than the members of second period (e.g., O and F) because second period elements have very small atomic size. Hence, there is tendency of electron-electron repulsion, which resultss in less evolution of energy in the formation of correcsponding anion. The first ionisation energy of Na, Mg,AI and Si are in the order of:

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NARAYNA-PERIODIC TABLE -All Questions
  1. Which of the following statements is incorrect ?

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  2. S-1 : Formation of Mg^(2+) and Al^(3+) , both require the absorption o...

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  3. N(0)//2 atoms of X(g) are converted into X^(+) (g) by energy E(1) . N(...

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  4. Which of the following triads have approximately equal size ?

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  5. Ionic radii of :

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  6. When the following five anions are arranged in order of decreasing ion...

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  7. (a),(b) and (c) are elements in the second short period. Oxide of (a) ...

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  8. Sizes of the second and third row transition elements are almost the s...

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  9. EN of the element (A) is E(1) and EA is E(2) hence IP will be :

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  10. For the element X, student Surbhi measured its radius as 102 nm, Mr. G...

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  11. The effective nuclear charge on the added electron in F-atom , in the ...

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  12. Covalent radius of F is 0.72 A^(@) . Calculate its Allred-Rochow's ele...

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  13. Covalent radius of oxygen is 0.74 A^(@) and its A .R. electronegativi...

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  14. There are four elements 'P' , 'q' , 'r' and 's' having atomic numbers ...

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  15. Which of the following statements are correct? (i) Generally the ra...

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  16. The correct order of atomic radii of the following element Sm(z=62), E...

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  17. Consider the following ionization steps : M(g) rarr M^(+)(g) +e^(-),...

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  18. Which of the following show amphoteric behaviour?

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  19. In which of the following arrangements, the order is not correct accor...

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  20. Which of the following statement(s) is /are correct?

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