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Geometrical isomerism is shown by...

Geometrical isomerism is shown by

A

`[Ni(NH_(3))_(5)Br]^(+)`

B

`[Cr(NH_(3))_(4)(en)(H_(2)O)_(4)]^(3+)`

C

`[Co(en)_(3)]^(3+)`

D

`[Co(NH_(3))_(4)(en)]^(3+)`

Text Solution

Verified by Experts

(d) Gemetrical isomerism is exhibited by octahedral comlexes like `[Co(NH_(3))_(2)(en)_(2)^(3+)]`
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Assertion (A) Complexes of MX_(6) and MX_(5)L type (X and L are unidentate) do not show geometrical isomerism. Reason (R) Geometrical isomerism is not shown by complexes of coordination number 6.

Statement-1: Complexes of MX_(6)" and "MX_(5)L type (X and L are unidentate) do not show geometrical isomerism. Statement-2: Geometrical isomerism is not shown by complexes of coordination number 6.