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For the equilibrium 2NOBr(g) hArr2NO + B...

For the equilibrium `2NOBr(g) hArr2NO + Br_(2)(g)` , calculate the ratio `(K_(p))/(P)`, where P is the total pressure and `P_(Br_(2)) = (P)/(9)` at a certain temperature

A

`(1)/(3)`

B

`(1)/(9)`

C

`(1)/(27)`

D

`(1)/(81)`

Text Solution

Verified by Experts

The correct Answer is:
D

`{:(2NOBr(g)hArr,2NO(g)+,Br(g)),(p-((2p)/(9)+(p)/(9)),(2p)/(9),(p)/(9)),(=(6p)/(9),,):}`
and `K_(p) = ((p_(NO))^(2)xx(p_(Br_(2))))/((p_(NOBr))^(2)) =(((2p)/(9))^(2)xx((p)/(9)))/(((6p)/(9))^(2)) =(p)/(81)`
`:. (K_(p))/(p) = (1)/(81)`
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