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The resistance of 0.1 N solution of a sa...

The resistance of 0.1 N solution of a salt is found to be `2.5xx10^(3) Omega`. The equivalent conductance of the solution is (Cell constant `=1.15 cm^(-1)`)

A

`4.6 ohm^(-1) cm^(2)" equiv"^(-1)`

B

`5.6 ohm^(-1) cm^(2)" equive"^(-1)`

C

`6.6 ohm^(-1) cm^(2)" equiv"^(-1)`

D

`7.6 ohm^(-1) cm^(2)" equiv"^(-1)`

Text Solution

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The correct Answer is:
To solve the problem of finding the equivalent conductance of a 0.1 N solution of a salt with a resistance of \(2.5 \times 10^3 \, \Omega\) and a cell constant of \(1.15 \, \text{cm}^{-1}\), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Formula for Equivalent Conductance**: The equivalent conductance (\( \Lambda \)) is given by the formula: \[ \Lambda = \frac{\kappa \times 1000}{C} \] where \( \kappa \) is the conductivity and \( C \) is the concentration in normality. 2. **Calculate Conductance**: Conductance (\( G \)) is the reciprocal of resistance (\( R \)): \[ G = \frac{1}{R} \] Given \( R = 2.5 \times 10^3 \, \Omega \): \[ G = \frac{1}{2.5 \times 10^3} = 0.0004 \, \text{S} \, (\text{Siemens}) \] 3. **Calculate Conductivity**: The conductivity (\( \kappa \)) can be calculated using the cell constant (\( k \)) and conductance (\( G \)): \[ \kappa = k \times G \] Given \( k = 1.15 \, \text{cm}^{-1} \): \[ \kappa = 1.15 \times 0.0004 = 0.00046 \, \text{S/cm} \] 4. **Substitute Values into the Equivalent Conductance Formula**: Now, substitute the values of conductivity and concentration into the equivalent conductance formula: \[ \Lambda = \frac{0.00046 \times 1000}{0.1} \] \[ \Lambda = \frac{0.46}{0.1} = 4.6 \, \text{S cm}^{-1} \text{equivalent}^{-1} \] 5. **Final Answer**: The equivalent conductance of the solution is: \[ \Lambda = 4.6 \, \text{S cm}^{-1} \text{equivalent}^{-1} \] ### Summary: The equivalent conductance of the 0.1 N solution of salt is \( 4.6 \, \text{S cm}^{-1} \text{equivalent}^{-1} \).

To solve the problem of finding the equivalent conductance of a 0.1 N solution of a salt with a resistance of \(2.5 \times 10^3 \, \Omega\) and a cell constant of \(1.15 \, \text{cm}^{-1}\), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Formula for Equivalent Conductance**: The equivalent conductance (\( \Lambda \)) is given by the formula: \[ \Lambda = \frac{\kappa \times 1000}{C} ...
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