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The emf of the cell involving the reacti...

The emf of the cell involving the reaction
`2Ag^(+) (aq)+H_(2)(g) rarr 2Ag(s)+2H^(+) (aq)` is `0.080 V`.
The standard oxidation potential od silver electrode is

A

0.80 V

B

0.40 V

C

`-0.80 V`

D

0.20 V

Text Solution

Verified by Experts

The correct Answer is:
C

From the equation, give cell represented as
`H_(2)|H^(+) (aq) ||Ag^(+) (aq)| Ag`
Hence, `E_("cell")=E_(Ag^(+)//Ag)-E_(H^(+)//1/2 H_(2))`
or `0.80=E_(Ag^(+)//Ag)-0.0`
`:. E_(Ag^(+)//Ag)=0.80 V`
Hence, `E_("oxi")=-0.80 V`
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