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Among the following lanthanoid ions, the...

Among the following lanthanoid ions, the paramagnetic ion is

A

`Yb^(2+)`

B

`Eu^(2+)`

C

`Lu^(3+)`

D

`Ce^(4+)`

Text Solution

Verified by Experts

The correct Answer is:
B

The valence shell electronic configuration of the given ions are
`Yb=[Xe]4f^(14)6s^(2)impliesYb^(2+)=[Xe]4f^(14)implies` No unpaired `e^(-)`
`Eu=[Xe]4f^(7)6s^(2)impliesEu^(2+)=[Xe]4f^(7)implies7` unpaired `e^(-)`
`Lu=[Xe]4f^(14)5d^(1)6s^(2)impliesLu^(3+)=[Xe]4f^(14)implies` No unpaired `e^(-)`
`Ce=[Xe]4f^(1)5d^(1)6s^(2)impliesCe^(4+)=[Xe]implies` No unpaired `e^(-)`
Hence, `Eu^(2+)` is paramagnetic as it contains 7 unpaired electrons.
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