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Larger number of oxidation states are ex...

Larger number of oxidation states are exhibited by the actinoids then those by the lanthanoids, the main reason being

A

4f orbitals are more diffused than the 5f orbitals

B

lesser energy difference between 5f and 6d than between 4f and 5d orbitals

C

more energy difference between 5 f and 6d than between 4f and 5d orbitals

D

more reactive nature of the actinoids than the lanthanoids

Text Solution

Verified by Experts

The correct Answer is:
B

Lanthanoids `[Xe]4f^(1-14)5d^(0-1)6s^(2)`
Actinoids `[Rn]5f^(1-14)6d^(0-1)7s^(2)`
Lanthanoids and actinoids use core d and f-orbitals also to show higher oxidation state. As actinolds have comparatively low energy difference between f and d-orbitals, thus show more oxidation states.
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