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Cold and dil. KMnO(4) reacts with but-2-...

Cold and dil. `KMnO_(4)` reacts with but-2-ene to form

A

ethane-1, 2-diol

B

butane-1, 4-diol

C

butane-1, 3-diol

D

butane-2, 3-diol

Text Solution

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The correct Answer is:
To solve the question of what product is formed when cold and dilute KMnO4 reacts with but-2-ene, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant**: - The reactant is but-2-ene, which has the structure: \[ \text{CH}_3-\text{C}=\text{C}-\text{CH}_3 \] - This structure shows that there is a double bond between the second and third carbon atoms. 2. **Understand the Reaction Conditions**: - The reaction is carried out with cold and dilute KMnO4. This reagent is known for its ability to perform syn-dihydroxylation of alkenes, which means it adds hydroxyl (OH) groups across the double bond. 3. **Reaction Mechanism**: - When but-2-ene reacts with cold and dilute KMnO4, the double bond will be converted into a single bond, and two hydroxyl (OH) groups will be added to the carbon atoms that were involved in the double bond. - The reaction can be represented as: \[ \text{CH}_3-\text{C}=\text{C}-\text{CH}_3 + \text{KMnO}_4 \rightarrow \text{CH}_3-\text{C(OH)}-\text{C(OH)}-\text{CH}_3 \] 4. **Draw the Product Structure**: - The product will have the structure: \[ \text{CH}_3-\text{C(OH)}-\text{C(OH)}-\text{CH}_3 \] - This indicates that both carbon atoms that were part of the double bond now have a hydroxyl group attached. 5. **Name the Product**: - The product formed is a diol, specifically a vicinal diol because the hydroxyl groups are on adjacent carbons. - The IUPAC name for this compound is 2,3-butanediol. 6. **Final Answer**: - Therefore, the product formed when cold and dilute KMnO4 reacts with but-2-ene is **2,3-butanediol**.

To solve the question of what product is formed when cold and dilute KMnO4 reacts with but-2-ene, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant**: - The reactant is but-2-ene, which has the structure: \[ \text{CH}_3-\text{C}=\text{C}-\text{CH}_3 ...
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Knowledge Check

  • One mole of acidic KMnO_(4) reacts with :

    A
    `(5)/(3) " mol of " FeC_(2)O_(4)`
    B
    `(5)/(2) " mol of " SO_(2)`
    C
    4 mol of FeS
    D
    1 mol of `H_(2)SO_(4)`
  • Hot and conc. KMnO_4 at 373-383 K reacts with pent - 2- ene to form

    A
    propionic acid only
    B
    ethonoic acid only
    C
    a mixture of propionic acid and ethanoic acid
    D
    a mixture of butanoic and formic acid
  • Cold and dil. Alk. KMnO_(4) will oxidise acetylene to

    A
    Ethylene glycol
    B
    Ethyl alcohol
    C
    Oxalic acid
    D
    Acetic acid
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