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When nitrobenzene is treated with Br(2)...

When nitrobenzene is treated with `Br_(2)` in presence of `FeBr_(3)`, the major product formed is `m-`bromo`-`nitrobenzene. Statement which is related to obtain the `m-`isomer is

A

the electron density on meta-carbon is less that on ortho and para-positions

B

the intermediate carbonium ion formed after initial attack of `Br^(+)` at the meta-position is least destabilised

C

lose of aromaticity when `Br^(+)` attacks at the ortho and para-positions and not at meta-position

D

easier loss of `H^(+)` to regain aromaticity from the meta-position than from ortho and para-positions

Text Solution

Verified by Experts

The correct Answer is:
B

`-NO_(2)` is a m-directing and deactivating group, hence `sigma`-complex is formed by attack of `Br^(+)` at meta-position will be most stable.
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