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The true order of reactivity towards S(N...

The true order of reactivity towards `S_(N)1` reaction is

A

vinyl chloride `gt` allyl chloride `gt` isopropyl chloride

B

allyl chloride `gt` isopropyl chloride `gt` vinyl chloride

C

vinyl chloride `gt` isopropyl chloride `gt` allyl chloride

D

isopropyl chloride `gt` vinyl chloride `gt` allyl chloride

Text Solution

Verified by Experts

The correct Answer is:
B
Vinyl chloride is relatively less reactive

While allyl chloride is very reactive due to stabilisation of allyl carbonium ion by resonance.
`CH_(2)=CH-overset(+)CH_(2)harroverset(+)CH_(2)-CH=CH_(2)`
Isopropyl chloride in between them is reactivity towards `S_(N)1`.
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