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For the reaction mechanism of the reacti...

For the reaction mechanism of the reaction
`{:(2NO(g)+2H_(2)(g))toN_(2)(g)+2H_(2)O(g):}`
`{:("Step I":2NOoverset(k_(1))hArrN_(2)O_(2) K_(eq)"(fast)")
("Step II:"N_(2)O_(2)+H_(2)overset(k_(2))rarrN_(2)O+H_(2)O"(slow)")
("Step III:"N_(2)O+H_(2)overset(k_(3))rarrrN_(2)+H_(2)O"(fast)"):}`
Expression of rate of reaction is
(Take `K_(eq) xx k_(2) = k')`

A

`k'[NO]^(2)[H_(2)]`

B

`k'N_(2)O_(2)[H_(2)]`

C

`k'N_(2)O[H_(2)]`

D

`k'N_(2)O_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A
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For the reaction mechanism of the reaction {:(2NO(g),+,2H_(2)(g)),(to N_(2)(g),+,2H_(2)O(g)):} {:("Step I",2NO,overset(k_(1))hArr,N_(2)O_(2),,,K_(eq)"(fast)"),("Step II",N_(2)O_(2)+H_(2),overset(k_(2))rarr,N_(2)O+H_(2)O,,"(slow)"),("Step III",N_(2)O+H_(2),overset(k_(3))rarrr,N_(2)+H_(2)O,,"(fast)"):} Expression of rate of reaction is (Take K_(eq) xx k_(2) = k')

The mechanism of the reaction 2NO(g)+H_(2)(g)rarrN_(2)(g)+2H_(2)O(g) , is: Step1: 2NO(g)+H_(2)(g)overset(("slow"))rarrN_(2)+H_(2)O_(2) Step2: H_(2)O_(2)+H_(2)overset("fast")rarr2H_(2)O

The mechanism of the reaction 2NO + O_(2) rarr 2NO_(2) is NO + NO underset(k_(-1))overset(k_(1))hArr N_(2)O_(2) ("fast") N_(2)O_(2) + O_(2) overset(k_(2))rarr 2NO_(2) (slow) The rate constant of the reaction is

For the reaction 2H_(2) + 2NO rarr N_(2) + 2H_(2)O , the following mechanism has been suggested : 2NO ? N_(2)O_(2) equilibrium constant K_(1) (fast) N_(2)O_(2) +H_(2) overset(k_(2)) rarr N_(2)O +H_(2)O (slow) N_(2) O +H_(2) overset(k_(3)) rarr N_(2)+H_(2)O (fast) Establish the rate law for given reaction.

consider the reaction . 2H_(2)(g)+2NO(g)to N_(2)(g)+2H_(2)O(g) The rate low of this reaction will be ,if mechanism of reaction is Step1: 2NOhArrN_(2)O_(2)["fast equilibrium"] Step2: N_(2)O_(2)+H_(2)toN_(2)O+H_(2)O["slow"] Step3: N_(2)O+H_(2)toN_(2)+H_(2)O["fast"]

For the reaction 2NO_(2(g))hArrN_(2)O_(4(g)),K_(p)//K_(c) is equal to

The possible mechanism for the reaction 2NO + 2H_(2) to N_(2) + 2H_(2)O is i) 2NO ltimplies N_(2)O_(2) ii) N_(2)O_(2) + H_(2) overset("slow")to N_(2)O+H_(2)O iii) N_(2)O + H_(2) overset("fast")to N_(2) + H_(2)O a) What is rate law for the reaction? b) What is the order of the reaction?

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