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Among TiF(6)^(2-), CoF(6)^(3-), Cu(2)C1(...

Among `TiF_(6)^(2-), CoF_(6)^(3-), Cu_(2)C1_(2)` and `NiC1_(4)^(2-)` (At. No. `Ti = 22, Co = 27, Cu = 29, Ni = 28)`, the colourless species are -

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In `[TiF_(6)]^(2-)` the titanium is in `+4` oxidation state having the electronic configuration `[Ar]^(18)3d^(0)4s^(0)`. Similarly in `Cu_(2)Cl_(2)` the copper is in `+1` oxidation state having the electronic configuration `[Ar]^(18)3d^(10)4s^(0)`. As they do not have any unpaired electrons for d- d transition, they are therefore colourless.
In `[NiCl_(4)]^(2-)` the nickel is in `+2` oxidation state and electronic configuration is `[Ar]^(18)3d^(8)4s^(0)`. As it has two unpaired electrons, so the complex is coloured. In `[CoF_(6)]^(3-)`, the cobalt is in `+3` oxidation state having electron configuration `[Ar]3d^(6)4s^(0)`. As it has four unpaired electron, so the complex is coloured.
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Among TiF_(6)^(2-), CoF_(6)^(3-), Cu_(2)Cl_(2) and NiCl_(4)^(2-) (At. No. Ti = 22, Co = 27, Cu = 29, Ni = 28) , the colourless species are -

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NARAYNA-D BLOCK & TRANSITION ELEMENTS-Level-VI (H.W)
  1. Among TiF(6)^(2-), CoF(6)^(3-), Cu(2)C1(2) and NiC1(4)^(2-) (At. No. T...

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  2. Generally transition elements from coloured salts due to the presence ...

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  3. Which of the following is amphoteric oxide? Mn(2)O(7),CrO(3),Cr(2)O(...

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  4. Interstitial compounds are formed when small atoms are trapped inside ...

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  5. Higher oxidation state of manganese in fluoride is +4 (MnF(4)) but hig...

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  6. Although zirconium belongs to 4d transition series and hafnium to 5d t...

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  7. Although Cr^(3+) and Co^(2+) ions have same number of unpaired electro...

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  8. The aqueous solution of transition metal salt changes colour from pink...

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  9. While Fe^(3+) is stable Mn^(3+) is not stable in acitic solution becau...

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  10. Which of the following transition metal oxides is(normally) neither ac...

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  11. The thermally unstable compounds are

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  12. Which one of the following reactions cannot occur?

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  13. Which of these are liquids at room temperature ?

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  14. The typical acidic oxides are

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  15. The compounds that undergo hydrolysis readily is/are

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  16. Which are the best suitable as coinage metals?

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  17. Paramagnetism is exhibited by :

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  18. In the form of dichromate, Cr(VI) is a strong oxidising agent in acidi...

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  19. The diamagnetic compounds is/are

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  20. The colour of the transition metal ions is due to

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  21. Select the correct statement(s) with respect to oxides and oxoanions o...

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