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Statement-1 : The number of paired elect...

Statement-1 : The number of paired electrons in the following gaseouos ions `Mn^(3+) , Cr^(3+) , V^(3+)` and `Ti^(3+)` are `4,3,2` and `1` respectively.
Statement-2 : `Cr^(3+)` is most stable in aqueous solution among these ions.
(A) Statement-1 is True, Statement-2 is True: Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True: Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

Text Solution

Verified by Experts

`Mn^(3+) = [Ar]^(18)3d^(4), Cr^(+3) = [Ar]^(18)3d^(3), V^(3+) = [Ar]^(18) 3d^(2), Ti^(3+) = [Ar]^(18)3d^(1)Cr^(3+)` is most stable in aqueous solution because it has half filed `t_(2g)^(3)` energy level of `3d` orbitals in octahedral crystal field spliting and accoding to crystals field theory (CFT) it has highest value of CFSE i.e. `1.2.D_(O)`.
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NARAYNA-D BLOCK & TRANSITION ELEMENTS-Level-VI (H.W)
  1. Statement-1 : The number of paired electrons in the following gaseouos...

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  2. Generally transition elements from coloured salts due to the presence ...

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  3. Which of the following is amphoteric oxide? Mn(2)O(7),CrO(3),Cr(2)O(...

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  4. Interstitial compounds are formed when small atoms are trapped inside ...

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  5. Higher oxidation state of manganese in fluoride is +4 (MnF(4)) but hig...

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  6. Although zirconium belongs to 4d transition series and hafnium to 5d t...

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  7. Although Cr^(3+) and Co^(2+) ions have same number of unpaired electro...

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  8. The aqueous solution of transition metal salt changes colour from pink...

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  9. While Fe^(3+) is stable Mn^(3+) is not stable in acitic solution becau...

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  10. Which of the following transition metal oxides is(normally) neither ac...

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  11. The thermally unstable compounds are

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  12. Which one of the following reactions cannot occur?

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  13. Which of these are liquids at room temperature ?

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  14. The typical acidic oxides are

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  15. The compounds that undergo hydrolysis readily is/are

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  16. Which are the best suitable as coinage metals?

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  17. Paramagnetism is exhibited by :

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  18. In the form of dichromate, Cr(VI) is a strong oxidising agent in acidi...

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  19. The diamagnetic compounds is/are

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  20. The colour of the transition metal ions is due to

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  21. Select the correct statement(s) with respect to oxides and oxoanions o...

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